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Sodium-Metal-Promoted Reductive 1,2-syn-Diboration of Alkynes with Reduction-Resistant Trimethoxyborane

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Reductive 1,2-diboration of alkynes has been accomplished by means of sodium dispersion in the presence of trimethoxyborane as a reduction-resistant boron electrophile. Two boron moieties can be in... Click to show full abstract

Reductive 1,2-diboration of alkynes has been accomplished by means of sodium dispersion in the presence of trimethoxyborane as a reduction-resistant boron electrophile. Two boron moieties can be in...

Keywords: diboration alkynes; trimethoxyborane; reduction resistant; sodium metal

Journal Title: Bulletin of the Chemical Society of Japan
Year Published: 2020

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