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Synthesis and Light-absorption Characteristics of Thiophene Derivatives Bearing Ferrocenylthiocarbonyl Groups#

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Thiophene-based dyes bearing two ferrocenylcarbonyl groups were obtained from a short synthesis involving direct arylations of the thiophene rings. A subsequent thionation of the carbonyl groups resulted in the formation… Click to show full abstract

Thiophene-based dyes bearing two ferrocenylcarbonyl groups were obtained from a short synthesis involving direct arylations of the thiophene rings. A subsequent thionation of the carbonyl groups resulted in the formation of new thiophene-based dyes bearing two ferrocenylthiocarbonyl groups. These dyes absorb in a wide range of the visible spectrum due to their π–π* and d–π* transitions, and show a remarkable red-shift of the absorption band relative to their carbonyl analogues without increasing the molecular size.

Keywords: absorption; absorption characteristics; synthesis light; characteristics thiophene; light absorption; ferrocenylthiocarbonyl groups

Journal Title: Chemistry Letters
Year Published: 2017

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