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Effects of Selenium Atoms on [1]Benzochalcogenopheno[3,2-b][1]benzochalcogenophene-based Organic Semiconductors#

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Effects of selenium substitution on [1]benzothieno[3,2-b][1]benzothiophene (BTBT) on transport properties were examined by comparison of 2,7-di-tert-butyl derivatives of BTBT and newly synthesized [1]benzoselenopheno[3,2-b][1]benzoselenophene (BSBS). The single-crystal field-effect transistors of the… Click to show full abstract

Effects of selenium substitution on [1]benzothieno[3,2-b][1]benzothiophene (BTBT) on transport properties were examined by comparison of 2,7-di-tert-butyl derivatives of BTBT and newly synthesized [1]benzoselenopheno[3,2-b][1]benzoselenophene (BSBS). The single-crystal field-effect transistors of the BSBS derivative showed slightly higher mobility than that of the BTBT counterpart, which is explained by the solid-state electronic structure estimated from the packing structure elucidated by single-crystal X-ray analysis.

Keywords: selenium atoms; atoms benzochalcogenopheno; benzochalcogenopheno benzochalcogenophene; benzochalcogenophene based; based organic; effects selenium

Journal Title: Chemistry Letters
Year Published: 2017

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