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Preparation of Dithienogermole-containing Polysilsesquioxane Films for Sensing Nitroaromatics

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Polysilsesquioxane films prepared by the copolymerization of dithienogermole dichloride (DTG-Cl) and bis(triethoxysilyl)ethane (BTESE) exhibited sensing properties towards nitroaromatic compounds. These films also responded to aniline, a potential interfering matrix. However,… Click to show full abstract

Polysilsesquioxane films prepared by the copolymerization of dithienogermole dichloride (DTG-Cl) and bis(triethoxysilyl)ethane (BTESE) exhibited sensing properties towards nitroaromatic compounds. These films also responded to aniline, a potential interfering matrix. However, selective sensing of nitrobenzene was possible and the film containing 2,6-dithienyldithienogermole as the sensing fluorophore underwent photoluminescence quenching only with nitrobenzene, but not with aniline.

Keywords: containing polysilsesquioxane; polysilsesquioxane; films sensing; preparation dithienogermole; polysilsesquioxane films; dithienogermole containing

Journal Title: Chemistry Letters
Year Published: 2017

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