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We have found that some vanadium complexes worked as effective catalysts toward reduction of molecular dinitrogen into silylamine under ambient reaction conditions, where up to 24 equiv of N(SiMe3)3 are… Click to show full abstract
We have found that some vanadium complexes worked as effective catalysts toward reduction of molecular dinitrogen into silylamine under ambient reaction conditions, where up to 24 equiv of N(SiMe3)3 are produced based on the vanadium atom. This is the first successful example of the vanadium-catalyzed transformation of nitrogen gas into ammonia equivalent under mild reaction conditions.
Keywords:
silylamine ambient;
reaction conditions;
molecular dinitrogen;
dinitrogen silylamine;
reaction;
reduction molecular
Journal Title: Chemistry Letters
Year Published: 2017
Link to full text (if available)
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Journal Title: Chemistry Letters
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!