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Hierarchically Porous Cellulose Monolith Prepared by Combination of Ice-template Method and Non-solvent-induced Phase Separation Method

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Hierarchically cellulose monoliths were successfully prepared by non-solvent-induced phase separation (NIPS) without any template. Phase separation was induced by adding ethyl acetate into a cellulose/LiCl-DMAc system. The obtained cellulose monolith… Click to show full abstract

Hierarchically cellulose monoliths were successfully prepared by non-solvent-induced phase separation (NIPS) without any template. Phase separation was induced by adding ethyl acetate into a cellulose/LiCl-DMAc system. The obtained cellulose monolith with a surface area of 30 m2 g−1 owned both mesoporous and macroporous structures. The pore size of the cellulose monolith could be easily tuned by changing the cellulose concentration. Moreover, the cellulose monoliths showed excellent mechanical properties.

Keywords: cellulose monolith; phase separation; non solvent; method

Journal Title: Chemistry Letters
Year Published: 2017

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