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Synthesis, Properties, and Reactivities of Ruthenium(II) Carbonyl 5,15-Diazaporphyrins

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We have succeeded in the synthesis of ruthenium(II) carbonyl 5,15-diazaporphyrin complexes 2 having pyridines as axial ligands. The structures, properties, and reactivities under photoirradiation of 2 are compared with those… Click to show full abstract

We have succeeded in the synthesis of ruthenium(II) carbonyl 5,15-diazaporphyrin complexes 2 having pyridines as axial ligands. The structures, properties, and reactivities under photoirradiation of 2 are compared with those of the corresponding ruthenium porphyrins.

Keywords: ruthenium; ruthenium carbonyl; properties reactivities; synthesis properties

Journal Title: Chemistry Letters
Year Published: 2017

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