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CeO2-supported Cu (Cu/CeO2) acted as an effective heterogeneous catalyst for N-methylation of aniline with CO2 and H2, showing higher selectivity to N-methylaniline, mono-N-methylated aniline, than other catalysts tested. Cu sub-nanoparticles… Click to show full abstract
CeO2-supported Cu (Cu/CeO2) acted as an effective heterogeneous catalyst for N-methylation of aniline with CO2 and H2, showing higher selectivity to N-methylaniline, mono-N-methylated aniline, than other catalysts tested. Cu sub-nanoparticles are the main active species, and the CeO2 support plays an important role in suppression of over-N-methylation of N-methylaniline to N,N-dimethylaniline.
Keywords:
methylation;
ceo2 supported;
methylation aniline;
catalyst;
ceo2
Journal Title: Chemistry Letters
Year Published: 2017
Link to full text (if available)
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Journal Title: Chemistry Letters
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!