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A two-step transformation of α,β-unsaturated carboxylic acids to alkenylboronic esters has been achieved via thioesterification of carboxylic acids followed by rhodium-catalyzed decarbonylative borylation of thioesters. The latter reaction proceeds under… Click to show full abstract
A two-step transformation of α,β-unsaturated carboxylic acids to alkenylboronic esters has been achieved via thioesterification of carboxylic acids followed by rhodium-catalyzed decarbonylative borylation of thioesters. The latter reaction proceeds under mild conditions with broad functional-group tolerance, rendering a wide range of alkenylboronic esters easily accessible.
Keywords:
unsaturated carboxylic;
rhodium catalyzed;
carboxylic acids;
transformation unsaturated;
acids alkenylboronic;
alkenylboronic esters
Journal Title: Chemistry Letters
Year Published: 2017
Link to full text (if available)
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Journal Title: Chemistry Letters
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!