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Photoexcited electron-transfer properties of C60 film on graphite and on Au(111) interfaces studied by two-photon photoemission spectroscopy

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We have employed two-photon photoemission (2PPE) spectroscopy to observe photoinduced charge transfer at C60 fullerene thin films formed on graphite and Au(111) substrates. From the analysis of the 2PPE intensities… Click to show full abstract

We have employed two-photon photoemission (2PPE) spectroscopy to observe photoinduced charge transfer at C60 fullerene thin films formed on graphite and Au(111) substrates. From the analysis of the 2PPE intensities of molecular-derived unoccupied states, it is revealed that the photoexcited electron transfer from graphite substrate to C60 is suppressed compared to C60 on Au(111), owing to inert properties of graphite surfaces.

Keywords: two photon; photoexcited electron; graphite 111; transfer; spectroscopy; photon photoemission

Journal Title: Chemistry Letters
Year Published: 2017

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