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Crystal Structure-dependent Thermal Stability and Catalytic Performance of AuRu3 Solid-solution Alloy Nanoparticles

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We describe the first investigation into the influence of the crystal structure of AuRu3 alloy nanoparticles (NPs) on their thermal stability and catalytic properties. The hexagonal close-packed (hcp)-AuRu3 alloy NPs… Click to show full abstract

We describe the first investigation into the influence of the crystal structure of AuRu3 alloy nanoparticles (NPs) on their thermal stability and catalytic properties. The hexagonal close-packed (hcp)-AuRu3 alloy NPs show better thermal stability than the face-centered cubic (fcc)-AuRu3 alloy NPs. The difference in catalytic properties was investigated through the oxygen evolution reaction. Both fcc- and hcp-AuRu3 alloy NPs show onset potentials comparable to Ru NPs. However, the hcp alloy NPs show higher durability than the fcc alloy NPs.

Keywords: alloy nps; crystal structure; alloy; thermal stability

Journal Title: Chemistry Letters
Year Published: 2018

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