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Formation of Metal-coordinated Doubly Chelating Pentadentate Ligands by the Reactions of [MoH4(Ph2PCH2CH2PPh2)2] with Organohydrodisilanes

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Thermal reaction of [MoH4(dppe)2] (dppe = Ph2PCH2CH2PPh2) with RR′HSiSiHRR′ (R = Ph, Me, t-Bu; R′ = Me, H) occurs with formation of molybdenum silyl complexes, [MoH3{Si(R)[Ph2PCH2CH2P(Ph)C6H4-o]2}]... Click to show full abstract

Thermal reaction of [MoH4(dppe)2] (dppe = Ph2PCH2CH2PPh2) with RR′HSiSiHRR′ (R = Ph, Me, t-Bu; R′ = Me, H) occurs with formation of molybdenum silyl complexes, [MoH3{Si(R)[Ph2PCH2CH2P(Ph)C6H4-o]2}]...

Keywords: formation metal; coordinated doubly; chelating pentadentate; metal coordinated; pentadentate ligands; doubly chelating

Journal Title: Chemistry Letters
Year Published: 2018

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