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The iridium-catalyzed direct C–H borylation of ring-fused (hetero)arenes afforded borylated products in a peri-selective manner, directed by a proximal hydrosilyl group. Further selective transformations of the boryl and silyl groups… Click to show full abstract
The iridium-catalyzed direct C–H borylation of ring-fused (hetero)arenes afforded borylated products in a peri-selective manner, directed by a proximal hydrosilyl group. Further selective transformations of the boryl and silyl groups enabled the synthesis of various multisubstituted (hetero)arenes, such as 1,8-disubstituted naphthalenes and 3,4-diarylindole.
Keywords:
ring fused;
hetero arenes;
iridium catalyzed;
hetero;
fused hetero;
borylation ring
Journal Title: Chemistry Letters
Year Published: 2018
Link to full text (if available)
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Journal Title: Chemistry Letters
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!