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Jumping Crystals of Stacked Planar Cobalt Complexes: Thermosalient Effect Promoted by Hydrogen-bonded Lattice Solvent Release

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Square-planar cobalt complexes, 2,2′-((1E,1′E)-(((Z)-ethene-1,2-diyl)bis(azaneylylidene))bis(ethan-1-yl-1-ylidene))diphenolate cobalt(II) hemisolvate [CoL]·0.5solv (solv = MeOH for 1, EtOH for 2), ... Click to show full abstract

Square-planar cobalt complexes, 2,2′-((1E,1′E)-(((Z)-ethene-1,2-diyl)bis(azaneylylidene))bis(ethan-1-yl-1-ylidene))diphenolate cobalt(II) hemisolvate [CoL]·0.5solv (solv = MeOH for 1, EtOH for 2), ...

Keywords: cobalt; planar cobalt; cobalt complexes; stacked planar; jumping crystals; crystals stacked

Journal Title: Chemistry Letters
Year Published: 2019

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