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Practical Synthesis of α,β-Alkynyl Ketones by Oxidative Alkynylation of Aldehydes with Hypervalent Alkynyliodine Reagents

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A practical, metal-free carbonyl C(sp2)–H oxidative alkynylation of aldehydes with hypervalent alkynyliodine reagents without the use of any catalysts is described for the synthesis of various α,β-... Click to show full abstract

A practical, metal-free carbonyl C(sp2)–H oxidative alkynylation of aldehydes with hypervalent alkynyliodine reagents without the use of any catalysts is described for the synthesis of various α,β-...

Keywords: alkynylation aldehydes; aldehydes hypervalent; oxidative alkynylation; alkynyliodine reagents; hypervalent alkynyliodine

Journal Title: Chemistry Letters
Year Published: 2020

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