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anti-Carbometalation of Alkynyl Sulfides Using Indium Tribromide and Ketene Silyl Acetals

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We developed the regioselective anti-carbometalation of alkynyl sulfides via the use of InBr3 and organosilicon nucleophiles to give β-mercaptoalkenylindium compounds. The structure of β-mercaptoal... Click to show full abstract

We developed the regioselective anti-carbometalation of alkynyl sulfides via the use of InBr3 and organosilicon nucleophiles to give β-mercaptoalkenylindium compounds. The structure of β-mercaptoal...

Keywords: anti carbometalation; using indium; alkynyl sulfides; sulfides using; carbometalation alkynyl

Journal Title: Chemistry Letters
Year Published: 2020

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