We introduce electrically poled small molecule assemblies that can serve as the active electro-optic material in nano-scale guided-wave circuits such as those of the silicon photonics platform. These monolithic organic… Click to show full abstract
We introduce electrically poled small molecule assemblies that can serve as the active electro-optic material in nano-scale guided-wave circuits such as those of the silicon photonics platform. These monolithic organic materials can be vacuum-deposited to homogeneously fill nanometer-size integrated-optics structures, and electrically poled at higher temperatures to impart an orientational non-centrosymmetric order that remains stable at room temperature. An initial demonstration using the DDMEBT molecule and corona poling delivered a material with the required high optical quality, an effective glass transition temperature of the order of ∼80°C, and an electro-optic coefficient of 20 pm/V.
               
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