LAUSR

Extending lasing wavelengths to the mid-infrared (MIR) spectrum is vital for both civilian and military applications; however, it remains challenging when employing oxide nonlinear optical crystals. In this study, we report the generation of MIR nanosecond pulses via difference frequency generation (DFG) with a near-IR pump using a newly designed langasite (LGS) crystal, La3(Nb0.6Ta0.4)0.5Ga5.5O14 (LGNT0.4), which incorporates birefringence dispersion management techniques with La3Ga5.5Nb0.5O14 (LGN) as a template. Due to the improved effective nonlinear coefficients and the maintained IR cutoff relative to LGN, the tunable DFG laser in LGNT0.4 extended from 4.24 to 6.84 μm, delivering a maximum pulse energy of 16.3 μJ at 5.02 μm. To the best of our knowledge, this is the first known oxide material capable of generating tunable nanosecond pulsed lasers beyond 6 μm at μJ-level energies, demonstrating promising potential for high-intensity MIR laser systems owing to its high laser damage threshold.