Abstract Metal chalcogenides are technologically important materials. Physical, chemical, electrical and mechanical properties of these materials can be fine-tuned by manipulating their shape, size and composition. Although several methods are… Click to show full abstract
Abstract Metal chalcogenides are technologically important materials. Physical, chemical, electrical and mechanical properties of these materials can be fine-tuned by manipulating their shape, size and composition. Although several methods are employed for their synthesis, single-source molecular precursor route has emerged as a versatile strategy for their synthesis and in controlling shape, size and composition of the material under moderate conditions. This chapter gives a brief coverage on the design and development of single-source molecular precursors which have been employed for the preparation of metal selenide/telluride nanocrystals and for deposition of thin films. The discussion includes synthesis of transition-, main group and f-block metal chalcogenolate and/or chalcogenide clusters as precursors and their conversion into metal chalcogenides in the form of thin films and nanostructures. Precursors for ternary metal chalcogenides are also included.
               
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