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Development of Catalysts for the Hydrogenation of the Aromatic Ring in Gasolines

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Liquid-phase hydrogenation of benzene ring in gasoline fractions of Atyrau Oil Refinery LLP (Kazakhstan) was studied. Monoand bimetallic catalysts on the basis of platinum metals on various carriers were synthesized.… Click to show full abstract

Liquid-phase hydrogenation of benzene ring in gasoline fractions of Atyrau Oil Refinery LLP (Kazakhstan) was studied. Monoand bimetallic catalysts on the basis of platinum metals on various carriers were synthesized. It was succeeded to reduce aromatic compounds content (totally) for “hydrogenate” fraction to 0.6–4.64 % (in initial gasoline – 11.2 %), and also to completely exclude the content of benzene from final sample or to reduce its quantity to 0.06 % (in the initial sample – 2.54 %). For the fraction “stable catalysate” benzene content was reduced to 0.15 wt. % (in the initial sample – 5.17 % wt.), benzene conversion – 97 %. For the fraction “hydrogenate” aromatic compounds content was decreased from 13.70 to 2.26 wt.%. For the “stable catalysate” an amount of aromatic compounds was reduced from 51.5 to 22.96 wt.%. At catalytic hydrodearomatization of the gasoline fractions octane number was not reduced.

Keywords: catalysts hydrogenation; hydrogenation aromatic; aromatic compounds; development catalysts; aromatic ring; ring gasolines

Journal Title: Chemical and Biochemical Engineering Quarterly
Year Published: 2018

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