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PdAg-decorated three-dimensional reduced graphene oxide-multi-walled carbon nanotube hierarchical nanostructures for high-performance hydrogen peroxide sensing

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High-performance electrochemical hydrogen peroxide (H 2 O 2 ) sensors based on PdAg nanoparticle-decorated reduced graphene oxide (rGO) and multi-walled carbon nanotube (MWCNT) hybrids were developed. The nanostructures were characterized… Click to show full abstract

High-performance electrochemical hydrogen peroxide (H 2 O 2 ) sensors based on PdAg nanoparticle-decorated reduced graphene oxide (rGO) and multi-walled carbon nanotube (MWCNT) hybrids were developed. The nanostructures were characterized using transmission electron microscopy, scanning electron microscopy, energy-dispersive spectroscopy, thermogravimetric analysis, Fourier transform spectroscopy, and x-ray diffraction techniques. It was found that introduction of MWCNT in the catalyst layer improved the sensitivity and widened the linear range. Sensitivities of 393.2, 437.1, and 576.6 µA/mM/cm 2 were obtained for PdAg/rGO–MWCNT (2:1), PdAg/rGO–MWCNT (1:1), and PdAg/rGO–MWCNT (1:2), respectively. Furthermore, hierarchical structure of rGO–MWCNT nanohybrids enabled the detection of H 2 O 2 up to 80 mM.

Keywords: rgo; mwcnt; microscopy; pdag; spectroscopy; high performance

Journal Title: MRS Communications
Year Published: 2018

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