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Antioxidant Activity Coefficient, Mechanism, and Kinetics of Different Derivatives of Flavones and Flavanones Towards Superoxide Radical

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●– ●– room temperature. The scavenging of the radical was monitored by the decrease in anodic or/and cathodic currents while linearly increasing the concentration of the flavonoid. The strength of… Click to show full abstract

●– ●– room temperature. The scavenging of the radical was monitored by the decrease in anodic or/and cathodic currents while linearly increasing the concentration of the flavonoid. The strength of interaction was quantified in terms of the binding constant ( k b ) values ranging from 1 × 10 2 and 5 × 10 3 M –1 . The antioxidant activity coefficient ( k ao ) was calculated from the linear part of the plot of ‘current decrease vs. flavonoid concentration’. Radical scavenging mechanism of the antioxidant was proposed and discussed in terms of the structure activity relationship. Nicholson-Shain method was employed to estimate the bimolecular homogeneous kinetics and on this basis control use of antioxidant is pointed out.

Keywords: activity coefficient; antioxidant activity; activity; mechanism

Journal Title: Czech Journal of Food Sciences
Year Published: 2018

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