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Effect of Carbon Nanotubes on the Electrochemical Performance of LiFePO4 Particles in Lithium Ion Batteries

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The pure LiFePO4 (LFP) materials were successfully obtained via an effective and controllable hydrothermal method with the assistance of ethylene glycol (EG).Then, the LFP/carbon nanotubes (CNTs) composite was synthesized in… Click to show full abstract

The pure LiFePO4 (LFP) materials were successfully obtained via an effective and controllable hydrothermal method with the assistance of ethylene glycol (EG).Then, the LFP/carbon nanotubes (CNTs) composite was synthesized in the process of final heat treatment. X-ray diffraction (XRD) and transmission electron microscopy (TEM) were used to research the composition, morphology and structure of LFP/CNTs composite. Electrochemical performance tests demonstrated that the 4wt% carbon nanotubes composite exhibited the best discharge specific capacity. The special capacity was 154.6mAh/g at 0.1C, and it had any damping after 5 cycles. The particle size of initial LFP prepared by hydrothermal method with the assistance of EG is shorter than others. The LFP/CNTs composite formed a three-dimensional network structure that enhanced the electrochemical performance.

Keywords: electrochemical performance; effect carbon; carbon nanotubes; cnts composite

Journal Title: International Journal of Electrochemical Science
Year Published: 2017

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