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A high-performance carbon-carbon(C/C) Quasi-Solid-State Supercapacitor with Conducting Gel Electrolyte

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The development of the electric double-layer capacitors (EDLCs) that pursue for the advantages of easily carrying, no leaking and high capacitance has been a strong objective at the moment. Here… Click to show full abstract

The development of the electric double-layer capacitors (EDLCs) that pursue for the advantages of easily carrying, no leaking and high capacitance has been a strong objective at the moment. Here a new type gel electrolyte with a high special conductivity of 15.06 mS·cm -2 was fabricate by immersing polyacrylamide gel (PAM-G) matrix in 6 M KOH aqueous solution for 60 hours. As expected, the assembled quasi-solid-state supercapacitor based PAM-G electrolyte exhibits a specific capacitance (of 196 F·g -1 and 156 F·g -1 at the charge-discharge current density of 1 A·g -1 and 10 A·g -1 , respectively), maximum power of 10 kW·kg -1 along with energy density of 28.6 Wh·kg -1 (under the current density of 10 A·g -1 ), and the capacitance retention rate keeps 98% after 5000 cycles at 1 A·g -1 , demonstrating a high cycling stability, an excellent rate capability as well as a high specific capacitance of the device. The promising electrochemical performance could be attributed to the unique homogeneous and microporous three-dimensional structure of the PAM-G which can greatly enhance the permeability and transportation of different ions.

Keywords: gel electrolyte; solid state; capacitance; carbon; state supercapacitor; quasi solid

Journal Title: International Journal of Electrochemical Science
Year Published: 2018

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