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Saccharin-assisted Galvanostatic Electrodeposition of Nanocrystalline FeCo Films on a Flexible Substrate

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The electrodeposition of functional materials on a flexible substrate has become an interesting topic because of the current development of flexible devices, called flexible technology, for various electronic applications. This… Click to show full abstract

The electrodeposition of functional materials on a flexible substrate has become an interesting topic because of the current development of flexible devices, called flexible technology, for various electronic applications. This study investigated FeCo film electrodeposition on a flexible polyethylene coated with indium tin oxide using the galvanostatic technique. The obtained FeCo films have a very fine crystallite size with a uniform surface morphology that changed remarkably upon introduction of a saccharin additive and upon increasing the deposition temperature. The effect of the saccharin concentration and deposition temperature on the current efficiency and anomalous co-deposition of FeCo was discussed. In this work, electrodeposition from an electrolyte containing 1 g/L saccharin at a very high current efficiency and a low deposition temperature was successfully achieved. The obtained composition ratio indicated that saccharin could reduce the anomalous co-deposition of Fe and Co. This phenomenon was also observed at a high deposition temperature. These results convincingly show the high current efficiency and reduced anomalous characteristic of the saccharin-assisted electrodeposition of FeCo.

Keywords: saccharin; deposition temperature; electrodeposition; flexible substrate; feco films

Journal Title: International Journal of Electrochemical Science
Year Published: 2020

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