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Polymerizable Ionic Liquid-derived Non-precious Metal Catalyst Fe-N/C for Oxygen Reduction Reaction

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Polymerizable ionic liquid (PIL) of hydrolyzed vinyl imidazolium nitrate ([HVim]NO3) was used to prepare the non-precious metal catalyst (NPMC) of Fe-N/C. The material was characterized for catalytic performance toward oxygen… Click to show full abstract

Polymerizable ionic liquid (PIL) of hydrolyzed vinyl imidazolium nitrate ([HVim]NO3) was used to prepare the non-precious metal catalyst (NPMC) of Fe-N/C. The material was characterized for catalytic performance toward oxygen reduction reaction (ORR). The onset and half wave potential for ORR is 0.90 and 0.64 VRHE, respectively. The electrochemical tests show that the Fe-N/C material is a potential NPMC for ORR. Therefore, the PIL is a promising precursor for ORR catalyst free of noble metal.

Keywords: ionic liquid; non precious; precious metal; polymerizable ionic; metal catalyst; catalyst

Journal Title: International Journal of Electrochemical Science
Year Published: 2021

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