Per- and polyfluoroalkyl substances (PFAS) measurable in soil porewater authoritatively represent the mobile mass fraction critical to accurate assessment of leaching from source zones. This study evaluated PFAS occurrence in… Click to show full abstract
Per- and polyfluoroalkyl substances (PFAS) measurable in soil porewater authoritatively represent the mobile mass fraction critical to accurate assessment of leaching from source zones. This study evaluated PFAS occurrence in lysimeter-collected porewater samples for two depth intervals at a decades-old aqueous film-forming foam (AFFF)-impacted field site quarterly for a year. Notably, site-wide Log10 (∑PFAS) concentrations did not significantly differ among sampling events despite highly variable sample yields due to a heterogeneous and dynamic soil moisture regime. However, Log10 (∑PFAS) concentrations were significantly higher in the shallow interval concordant with higher mean soil concentrations and higher total organic carbon (TOC) reflecting net retention, which is supported by soil-to-groundwater annual mass discharge estimates less than 0.2% of the total source mass for any given PFAS. Interestingly, PFAS-specific Log10 (soil-to-porewater ratios) significantly increased with soil concentration in both depth intervals contrary to concentration dependence resulting from the saturation of sorption sites potentially implicating self-assembly as an additional operative retention mechanism. Overall, these data validate the use of suction lysimeters for short-term site characterization deployments and emphasize the importance of in situ porewater samples for interrogating PFAS transport within source zones.
               
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