LAUSR

This study investigates the synthesis, characterization, and optical properties of cobalt-doped ?-tricalcium phosphate (Co-?TCP) nanoparticles prepared via microwave refluxing and sintered at 1000?C for 2 hours. Incorporating Co2+ ions into the ?TCP structure significantly influences its microstructural and optical properties. X-ray diffraction analysis (XRD) reveals a contraction of the crystal lattice upon Co2+ doping, attributed to the substitution of larger Ca2+ ions (ionic radius 0.099 nm) with smaller Co2+ ions (ionic radius 0.074 nm). This reduces lattice parameters, cell volume, crystallinity, and smaller crystallite sizes. The degree of crystallinity decreases from 89.56% for pure ?-TCP to 57.81% for 3Co-?-TCP. Scanning electron microscopy (SEM) shows that Co2+ doping produces more homogeneous powder with enhanced interconnectivity while maintaining a spheroidal agglomerated structure. The average particle size decreases from approximately 300 nm for pure ?TCP to 246 nm for 3Co-?TCP. Fourier transform infrared spectroscopy confirms the successful integration of Co2+ ions into the ?TCP lattice, evidenced by peak broadening and intensity reduction. Notably, incorporating Co2+ ions induces a striking colour change from white to pink, with intensity proportional to cobalt concentration. UV-Vis spectroscopy reveals characteristic absorption peaks at 530 and 678 nm, associated with Co2+ electronic transitions. The unique optical properties of Co2+ ions doped in ?TCP open up new possibilities for its use in bioimaging and drug delivery systems