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Two series of nitrilotrismethylenephosphonic complexes of 3d elements, [MII(H2O)3{NH(CH2PO3H)3}]n (M = Cr–Zn) and Na8[MII{N(CH2PO3)3}]2nH2O (M = Co–Zn), are studied. A comparative analysis of their structural features showed the influence the… Click to show full abstract
Two series of nitrilotrismethylenephosphonic complexes of 3d elements, [MII(H2O)3{NH(CH2PO3H)3}]n (M = Cr–Zn) and Na8[MII{N(CH2PO3)3}]2nH2O (M = Co–Zn), are studied. A comparative analysis of their structural features showed the influence the Jahn–Teller effect has on the formation of the crystal structures, reactive capacities, and anticorrosive activities of these compounds.
Keywords:
complexes elements;
forming structure;
effects forming;
role electronic;
nitrilotrismethylenephosphonic complexes;
electronic effects
Journal Title: Bulletin of the Russian Academy of Sciences: Physics
Year Published: 2017
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Journal Title: Bulletin of the Russian Academy of Sciences: Physics
Year Published: 2017
Link to full text (if available)
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recommendations!