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Binary Polymer Systems Based on Polyvinylbutyral: FTIR Spectra, Conformational Dynamics, and Free Volume

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Local molecular dynamics of polymer systems based on polyvinylbutyral is studied via the IR Fourier spectroscopy of conformation-inhomogeneous probes. The compositions of the studied binary mixtures of polyvinylbutyral with polymethylmethacrylate… Click to show full abstract

Local molecular dynamics of polymer systems based on polyvinylbutyral is studied via the IR Fourier spectroscopy of conformation-inhomogeneous probes. The compositions of the studied binary mixtures of polyvinylbutyral with polymethylmethacrylate are 80: 20, 60: 40, 40: 60, and 20: 80. The temperatures of the secondary relaxation transitions and the difference between the enthalpies of conformation of the probe molecules in these systems are obtained. The effective sizes of mobile free-volume elements, the diffusion of which results in the transport of small molecules upon membrane gas separation, are estimated.

Keywords: binary polymer; free volume; systems based; based polyvinylbutyral; polymer systems

Journal Title: Bulletin of the Russian Academy of Sciences: Physics
Year Published: 2018

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