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A NH4I/tert-butyl hydroperoxide-promoted oxidation of tertiary N-aryl-N,N-dialkylamines in DMSO has been developed to access nitroaromatic compounds. This methodology involves sequential N-dealkylation reactions in one-pot and a radical pathway is proposed. Click to show full abstract
A NH4I/tert-butyl hydroperoxide-promoted oxidation of tertiary N-aryl-N,N-dialkylamines in DMSO has been developed to access nitroaromatic compounds. This methodology involves sequential N-dealkylation reactions in one-pot and a radical pathway is proposed.
Keywords:
hydroperoxide promoted;
nh4i tert;
nitroaromatic compounds;
tert butyl;
butyl hydroperoxide
Journal Title: Journal of Chemical Research
Year Published: 2017
Link to full text (if available)
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Journal Title: Journal of Chemical Research
Year Published: 2017
Link to full text (if available)
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recommendations!