In order to optimize the conditions for the biofuels production by a hydrotreatment process, three platinum catalysts supported on different zeolites were evaluated. The three zeolites used for the hydrotreatment… Click to show full abstract
In order to optimize the conditions for the biofuels production by a hydrotreatment process, three platinum catalysts supported on different zeolites were evaluated. The three zeolites used for the hydrotreatment of soybean oil were USY (CBV-780), H-? and ZSM-5, impregnated with 1 % platinum salt solution. The functional groups of the catalysts were analyzed by infrared transmission spectroscopy, the condition of the pores by scanning electron microscopy and, X-ray diffraction was employed to determine the crystal structure. Subsequently, these catalysts were employed to hydrotreat some soybean oil samples of 80 mL, in a 300 mL reactor, operating at 525 K, 2500 kPa, and a H2/N2 molar ratio of 30 % for 6 h. Some gas chromatography analyses carried out over the synthesized biofuels evidenced that Zeolite H-? presents the best characteristics for the production of a biofuel with the most similar properties to the currently employed fossil fuels.
               
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