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Parametric Calculations of Radiative Decay Rates for Magnetic Dipole and Electric Quadrupole Transitions in Tm IV, Yb V, and Er IV

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Semi-empirical transition probabilities for magnetic dipole (M1) and electric quadrupole (E2) emission lines have been derived from parametric studies of experimental energy levels in Tm3+ (Tm IV), Yb4+ (Yb V),… Click to show full abstract

Semi-empirical transition probabilities for magnetic dipole (M1) and electric quadrupole (E2) emission lines have been derived from parametric studies of experimental energy levels in Tm3+ (Tm IV), Yb4+ (Yb V), and Er3+ (Er IV), using Cowan codes. Results are compared with those existing from ab initio calculations or from more sophisticated semi-empirical calculations. Satisfactory agreements show that simple parametric calculations can provide good predictions on line intensities, provided that experimental levels are available, allowing reliable fits of energy parameters.

Keywords: calculations radiative; magnetic dipole; radiative decay; dipole electric; parametric calculations; electric quadrupole

Journal Title: Atoms
Year Published: 2018

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