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Facile Fabrication of Glycosylpyridyl-Triazole@Nickel Nanoparticles as Recyclable Nanocatalyst for Acylation of Amines in Water

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In this report, novel glycosylpyridyl-triazole@nickel nanoparticles (GPT-Ni) were successfully prepared via click chemistry and were fully characterized by various spectroscopy measurements. The as-prepared catalysts could be used as a recyclable… Click to show full abstract

In this report, novel glycosylpyridyl-triazole@nickel nanoparticles (GPT-Ni) were successfully prepared via click chemistry and were fully characterized by various spectroscopy measurements. The as-prepared catalysts could be used as a recyclable catalyst for the catalytic acylation of amines by employing N,N-dimethylacetamide (DMA), N,N-dimethylpropionamide (DMP), and N,N-dimethylformamide (DMF) as acylation reagents in water, providing the corresponding amides in good yields. The practicability of this methodology is highlighted by the good recyclability of the catalyst. A unique mechanism was proposed for the catalytic process.

Keywords: glycosylpyridyl triazole; acylation; acylation amines; nickel nanoparticles; triazole nickel

Journal Title: Catalysts
Year Published: 2020

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