LAUSR

Sulfur ylides are an important class of organic compounds due to their ability to perform many different transformations that can give diverse and interesting products with a high degree of complexity. Although metal-catalyzed transformations are frequent in this class of compounds, organocatalyzed transformations remain scarce. From initial works, this review aims to show organocatalyzed transformations from sulfur ylides, involving cyclopropanation and formal N–H, S–H, and C–H insertion reactions, including enantioselective versions. The proposed mechanisms and the modes of activation of these organocatalysts will be covered. Furthermore, advances in this area and potential challenges to be circumvented in the near future will also be discussed.