LAUSR

Organic semiconductor-based photoelectrodes are gaining significant attention in photoelectrochemical (PEC) value-added chemical production systems, which are promising architectures for solar energy harvesting. Organic semiconductors consisting of conjugated carbon–carbon bonds provide several advantages for PEC cells, including improved charge transfer, tunable band positions and band gaps, low cost, and facile fabrication using organic solvents. This review gives an overview of the recent advances in emerging single organic semiconductor-based photoelectrodes for PEC water splitting and the various strategies for enhancing their performance and stability. It highlights the importance of photoelectrodes based on donor–acceptor bulk heterojunction (BHJ) systems for fabricating efficient organic semiconductor-based solar energy-harvesting devices. Furthermore, it evaluates the recent progress in BHJ organic base photoelectrodes for producing highly efficient PEC value-added chemicals, such as hydrogen and hydrogen peroxide. Finally, this review highlights the potential of organic-based photoelectrodes for bias-free solar-to-chemical production, which is the ultimate goal of PEC systems and a step toward achieving reliable commercial technology.