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The current report contributes to the understanding of the stereoselectivity of chiral dirhodium(II) carboxylate catalysts carrying N-protected tert-leucine ligands. Investigating the possible effect of ligand stereo-purity on catalyst structure and… Click to show full abstract
The current report contributes to the understanding of the stereoselectivity of chiral dirhodium(II) carboxylate catalysts carrying N-protected tert-leucine ligands. Investigating the possible effect of ligand stereo-purity on catalyst structure and enantioselectivity was carried out. This was justified through a new X-ray crystal structure for Rh2(S,S,S,R-PTTL)4 diastereomer.
Keywords:
effect ligand;
ligand stereo;
chiral dirhodium;
structure;
stereo purity;
purity catalyst
Journal Title: Catalysts
Year Published: 2018
Link to full text (if available)
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Journal Title: Catalysts
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!