A detailed electrochemical study and investigation of a Fe-P glycine bath as a function of the temperature and glycine concentrations and current density, and their resulting corrosion and mechanical behavior… Click to show full abstract
A detailed electrochemical study and investigation of a Fe-P glycine bath as a function of the temperature and glycine concentrations and current density, and their resulting corrosion and mechanical behavior is presented. A low addition of glycine to the electrolyte led to a drastic increase of the P content. At low Fe-P deposition rates, heterogeneous rough deposits with morphological bumps and pores were observed. By increasing the Fe-P deposition rate, the number of pores were reduced drastically, resulting in smooth coatings. Increasing the P content led to the formation of nanocrystalline grains from an “amorphous-like” state. Coatings with higher P contents exhibited better corrosion resistance and hardening, most likely attributed to grain boundary strengthening.
               
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