LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

What Is the Real Clausius Statement of the Second Law of Thermodynamics?

Photo from wikipedia

In this paper, we first analyze the difference between the second law of thermodynamics and the laws in other disciplines. There are some phenomena in other disciplines similar to the… Click to show full abstract

In this paper, we first analyze the difference between the second law of thermodynamics and the laws in other disciplines. There are some phenomena in other disciplines similar to the Clausius Statement of the second law, but none of them has been accepted as the statement of a certain law. Clausius’ mechanical theory of heat, published in the nineteenth century, is then introduced and discussed in detail, from which it is found that Clausius himself regarded “Theorem of the equivalence of the transformation of heat to work, and the transformation of heat at a higher temperature to a lower temperature”, rather than “Heat can never pass from a colder to a warmer body without some other change”, as the statement of the second law of thermodynamics. The latter is only laid down as the fundamental principle for deriving the theorem of the equivalence of transformations. Finally, based on the theorem of the equivalence of transformations and the average temperature method, a general quantitative relation among the heat, the work, and the temperatures is obtained for arbitrary cycles, which is thus recommended as an alternative mathematic expression of the second law. Hence, the theorem of the equivalence of transformations is the real Clausius Statement of the second law of thermodynamics.

Keywords: law; thermodynamics; second law; statement second; law thermodynamics

Journal Title: Entropy
Year Published: 2019

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.