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Synergistic Enhancement of Ternary Poly(3,4-ethylenedioxythiophene)/Graphene Oxide/Manganese Oxide Composite as a Symmetrical Electrode for Supercapacitors

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A novel facile preparation of poly(3,4-ethylenedioxythiophene)/graphene oxide/manganese oxide (PEDOT/GO/MnO2) ternary composite as an electrode material for a supercapacitor was evaluated. The ternary composite was sandwiched together and separated by filter… Click to show full abstract

A novel facile preparation of poly(3,4-ethylenedioxythiophene)/graphene oxide/manganese oxide (PEDOT/GO/MnO2) ternary composite as an electrode material for a supercapacitor was evaluated. The ternary composite was sandwiched together and separated by filter paper soaked in 1 M KCl in order to investigate the supercapacitive properties. The ternary composite exhibits a higher specific capacitance (239.4 F/g) compared to PEDOT/GO (73.3 F/g) at 25 mV/s. The incorporation of MnO2 which act as a spacer in the PEDOT/GO helps to improve the supercapacitive performance by maximizing the utilization of electrode materials by the electrolyte ions. The PEDOT/GO/MnO2 ternary composite displays a specific energy and specific power of 7.9 Wh/kg and 489.0 W/kg, respectively. The cycling stability test revealed that the ternary composite is able to achieve 95% capacitance retention even after 1000 cycles due to the synergistic effect between the PEDOT, GO, and MnO2 that helps to enhance the performance of the ternary composite for supercapacitor application.

Keywords: graphene oxide; ethylenedioxythiophene graphene; ternary composite; electrode; poly ethylenedioxythiophene; oxide manganese

Journal Title: Energies
Year Published: 2018

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