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A Synergistic Effect of Potassium and Transition Metal Compounds on the Catalytic Behaviour of Hydrolysis Lignin in CO2-Assisted Gasification

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CO2-assisted gasification of carbon-based waste materials is one of the processes that both utilises waste carbon chemicals and produces CO, which is a highly sought after raw material. In this… Click to show full abstract

CO2-assisted gasification of carbon-based waste materials is one of the processes that both utilises waste carbon chemicals and produces CO, which is a highly sought after raw material. In this work, we aimed at finding and clarifying the synergistic effects of simultaneous potassium and Fe, Co, or Ni-driven catalysis. To reveal the behaviour of such systems, a series with different potassium loadings and a fixed second metal loading of 5 wt.% was prepared. The following methods were applied for this purpose: SEM, TEM, EDX, XRD, electron diffraction, and catalytic tests. The most active sample was found to be 3 wt.% K and 5 wt.% Co- or Fe-loaded hydrolysis lignin. The attained CO2 conversion was up to 92%, while the pure lignin sample demonstrated only 62% conversion under the same conditions.

Keywords: lignin; potassium; assisted gasification; hydrolysis lignin; co2 assisted

Journal Title: Energies
Year Published: 2023

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