A method for the reduction of aldehydes with pinacolborane catalyzed by pincer cobalt complexes based on a triazine backbone is developed in this paper. The presented methodology allows for the… Click to show full abstract
A method for the reduction of aldehydes with pinacolborane catalyzed by pincer cobalt complexes based on a triazine backbone is developed in this paper. The presented methodology allows for the transformation of several aldehydes bearing a wide range of electron-withdrawing and electron-donating groups under mild conditions. The presented procedure allows for the direct one-step hydrolysis of the obtained intermediates to the corresponding primary alcohols. A plausible reaction mechanism is proposed.
Keywords:
reaction;
reduction aldehydes;
cobalt catalyzed;
reduction;
catalyzed reduction;
aldehydes alcohols
Journal Title: International Journal of Molecular Sciences
Year Published: 2024
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Journal Title: International Journal of Molecular Sciences
Year Published: 2024
Link to full text (if available)
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recommendations!