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Poly (3,4-Ethylenedioxythiophene) (PEDOT) Nanofibers Decorated Graphene Oxide (GO) as High-Capacity, Long Cycle Anodes for Sodium Ion Batteries

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Conductive Poly (3,4-ethylenedioxythiophene) (PEDOT) nanofibers are uniformly deposited on ultrathin graphene oxide (GO) nanosheets via a simple and effective in situ polymerization process under ambient conditions. The as-prepared samples are… Click to show full abstract

Conductive Poly (3,4-ethylenedioxythiophene) (PEDOT) nanofibers are uniformly deposited on ultrathin graphene oxide (GO) nanosheets via a simple and effective in situ polymerization process under ambient conditions. The as-prepared samples are characterized by field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), Raman spectra, Fourier transforms infrared spectra (FTIR), and electrochemical measurements. The results indicate that the as-obtained PEDOT–GO hybrid (GDOT) achieves excellent sodium storage properties. When explored as a new inorganic/polymeric electrode for sodium ion batteries (SIBs), the GDOT exhibits a high reversible capacity (338 mAh g−1), good cycling stability (234 mAh g−1 after 400 cycles), and excellent rate capabilities (e.g., 62 mAh g−1 at 30 A g−1) due to their ultrathin structure as well as conductive network. This easily scale-up-able and effective strategy shows great potential for large-scale energy applications.

Keywords: graphene oxide; sodium ion; microscopy; pedot nanofibers; ethylenedioxythiophene pedot; poly ethylenedioxythiophene

Journal Title: Materials
Year Published: 2018

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