LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

Acid Leaching Extraction Mechanism of Aluminum and Iron Ions from Coal Gangue Based on CaF2 Assistance and Process Optimization

Photo from wikipedia

To reveal how CaF2 improves the dissolution ratios of aluminum and iron ions in coal gangue, CaF2 and hydrochloric acid are used to extract Al3+ and Fe3+ from the coal… Click to show full abstract

To reveal how CaF2 improves the dissolution ratios of aluminum and iron ions in coal gangue, CaF2 and hydrochloric acid are used to extract Al3+ and Fe3+ from the coal gangue calcined powder. The leaching ratios of Al3+ and Fe3+ are measured, and the filter residues are analyzed by BET, XRD, and SEM. The results show that adding 3% CaF2 could increase the extraction ratio of Al3+ from 62.96% to 92.10% under optimized conditions, and that of Fe3+ is increased from 85.12% to 95.73%. The mechanism of CaF2 as an auxiliary to improve the leaching ratio of Fe3+ is that HF reacts with the thin layers of gangue calcined powder containing silica to form soluble SiF4, thus forming pores that promote the diffusion of H+ and inner ions, improving the leaching ratios of Al3+ and Fe3+. Finally, the CaF2-assisted acid leaching process is optimized. The results showed that it is efficient and feasible to extract Al3+ and Fe3+ with the assistance of CaF2 and that HF has a catalytic effect in the reaction system. This work provides a reference for the next step of actual production.

Keywords: ions coal; al3 fe3; caf2; coal gangue; aluminum iron; iron ions

Journal Title: Materials
Year Published: 2023

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.