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Effect of Temperature and Impurity Content to Control Corrosion of 316 Stainless Steel in Molten KCl-MgCl2 Salt

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The corrosion resistance of 316 stainless steel (316SS) in molten KCl-MgCl2 salts was studied through static immersion corrosion at high temperatures. Below 600 °C, the corrosion rate of 316SS increased… Click to show full abstract

The corrosion resistance of 316 stainless steel (316SS) in molten KCl-MgCl2 salts was studied through static immersion corrosion at high temperatures. Below 600 °C, the corrosion rate of 316SS increased slowly with increasing temperature. When the salt temperature rises to 700 °C, the corrosion rate of 316SS increases dramatically. The corrosion of 316SS is mainly due to the selective dissolution of Cr and Fe at high temperatures. The impurities in molten KCl-MgCl2 salts could accelerate the dissolution of Cr and Fe atoms in the grain boundary of 316SS, and purification treatment can reduce the corrosivity of KCl-MgCl2 salts. Under the experimental conditions, the diffusion rate of Cr/Fe in 316SS changed more with temperature than the reaction rate of salt impurities with Cr/Fe.

Keywords: 316 stainless; kcl mgcl2; temperature; molten kcl; corrosion; salt

Journal Title: Materials
Year Published: 2023

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