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First Hydrogenation Enhancement in TiFe Alloys for Hydrogen Storage Doped with Yttrium

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The aim of this investigation was to improve the first hydrogenation of TiFe by adding yttrium. The compositions studied were TiFe + x wt.% Y with x = 4, 6,… Click to show full abstract

The aim of this investigation was to improve the first hydrogenation of TiFe by adding yttrium. The compositions studied were TiFe + x wt.% Y with x = 4, 6, and 8. From electron microscopy it was found that all alloys were multiphase with a matrix of TiFe phase containing less than 0.4 at.% of Y and a secondary phase rich in yttrium. When x increased, the chemical compositions of the matrix changed and the secondary phase changed. The sample with 8% of yttrium had the fastest kinetics. The hydrogen capacity increased with the amount of Y.

Keywords: tife; enhancement tife; hydrogenation enhancement; yttrium; first hydrogenation

Journal Title: Metals
Year Published: 2019

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