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Alkaloids and Selected Topics in Their Thermochemistry

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Alkaloid chemistry is varied and complex. Many alkaloids attract a great deal of interest because of their physiological activity, yet surprisingly little is known about the thermochemistry of these compounds,… Click to show full abstract

Alkaloid chemistry is varied and complex. Many alkaloids attract a great deal of interest because of their physiological activity, yet surprisingly little is known about the thermochemistry of these compounds, especially in the gas phase. In this paper, we investigate the thermochemical characteristics, specifically demethoxylation enthalpies rather than those derived from trans-methoxylation reactions, of a series of biologically relevant alkaloids in their condensed phase.

Keywords: alkaloids selected; chemistry; thermochemistry; selected topics; topics thermochemistry

Journal Title: Molecules
Year Published: 2021

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