Mineral expansive from FDG—flue-gas desulfurization—blended with calcium aluminate cement CAC was analyzed as mitigation shrinkage of alkali-activated residual mortars AAM. The AAM mortars were composed of red mud (RM) and… Click to show full abstract
Mineral expansive from FDG—flue-gas desulfurization—blended with calcium aluminate cement CAC was analyzed as mitigation shrinkage of alkali-activated residual mortars AAM. The AAM mortars were composed of red mud (RM) and bottom ash (BA), as precursors of a metakaolin MK-based system. MK replacement (0, 50, 70%) in alkaline solution (10M) and ratio 1:2 (binder/sand) was studied. Engineering properties were performed, and included mechanical strength, setting times, and dry shrinkage (HR 60%), as well as the microstructure formed at 7 d and 28 days. A total of 10% CAC-FGD dosage was the most efficient, reducing drying shrinkage by 23% and autogenous shrinkage by up to 30%. The findings showed that this addition also improved mechanical strength by approximately 16% at 28 days. Under the addition of CAC-FGD, the results suggest the presence of aluminosilicate gels of the (Na,C)-(A)-S-H type and the formation of ettringite, which are possibly responsible for ensuring good performance and a controlled expansion that, in turn, compensates for the shrinkage of the activated mortars.
               
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