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Fabrication of transition metal (TM = Fe, Co) difluorides–carbon nanocomposite films by magnetron co-sputtered deposition of Fe/Co and Teflon targets

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We present a general synthesis of transition metal difluorides (TMF2)–carbon nanocomposite films by magnetron co-sputtering the Fe/Co and polytetrafluoroethylene (Teflon) targets. The composites consist of binary TMF2 (TM = Fe,… Click to show full abstract

We present a general synthesis of transition metal difluorides (TMF2)–carbon nanocomposite films by magnetron co-sputtering the Fe/Co and polytetrafluoroethylene (Teflon) targets. The composites consist of binary TMF2 (TM = Fe, Co) nanoparticles with a crystallite size of ∼8 nm immersed in a carbon matrix. The antiferromagnetic nature of TMF2 nanoparticles with the Néel temperature T N of 40 K (TM = Co) and 78 K (TM = Fe) is confirmed. The ability to create the sputter-deposited TMF2–carbon nanocomposites may not only allow for possible energy applications but also provide a platform for investigating the particulate disordered antiferromagnets.

Keywords: carbon nanocomposite; transition metal; metal difluorides; films magnetron; nanocomposite films; teflon targets

Journal Title: Applied Physics Express
Year Published: 2021

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