Poly(diphenylene phthalide) (PDP) belongs to the class of carbocyclic organic electroactive polymers, which exhibits electric conductive properties when an external electric field and/or mechanical stress is applied. In this work,… Click to show full abstract
Poly(diphenylene phthalide) (PDP) belongs to the class of carbocyclic organic electroactive polymers, which exhibits electric conductive properties when an external electric field and/or mechanical stress is applied. In this work, the transport properties of thin-film layered lead–PDP–lead structures were experimentally studied in a wide temperature range. At sufficiently high temperatures, the current voltage characteristics are satisfactorily described in terms of the injection model of currents limited by the space charge. At temperatures below ≈8 K, a number of samples exhibit features that can be explained by the effect of induced superconductivity in a thin film of conducting polymer enclosed between two massive superconductors (lead).
               
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